b'C~ tn~ L~AbH UGIMI ZFEB1981 ~~d Sh~ Pdent st 81 13A2P6 ~~ 111111111111111111111111111111111~4 arl~s~ -- ~ ~~ M~IAI IW A L~OD ~ 1IW~ ~1~ Y 1YP Yn~JF~~IXe IrD USKC ~E ~ I~lol Iunl~ Yrt~l 1#J cfi)Y IUlm ~1~1 1#1 ~ taae Y tOY eYJ ~I~ Cnlll YI~ ~ tn/U1 Sdr~dZ~'"Y~ ·ig~l P0 ~t~~MY PIUI ~IP Mit I~ ]~ ADIY YIII I~ Me Y ~, m, pt F~nip Al~idll Mdg ~p WR ~UUIIDMI H1, In gq I~_ alp ~up~t d~ ~~o ~~lt Hn, nff Dq s.~· r ~ Wr o~n~ *I I ~ lo~or, g0 L~' -- I oil tm ~Mr/ Bi~F-Tko~l ~ Glta ~ne ~I ·~~d' bb II~ 1~; YPI~ ~BSIIUCI BP Rlu~~,,,,llM1E11 a, so ms II~ ac I~~~ ~at cP; ~ 91~ rrhl LI *~ *brulec~ o16a L I~· :YIY . ~ 0' 4~ 'd~ ~ ~ rrmond ~~ ~ ~· ~ L I~ Bm ol~ ·~ ol~~ ~~ n I~ P!hlr 0~ ·p~b~cl L isb 6~ a~ ~ ~I at IS, P~~ ~VM~I?S I~pl do tot LI ~lp Q ~) ~ ~I C~ ·d ~ o~dol ardrrd i ~6*d LI ~idb a~l C~Y YI~ ~lo, oop~ dtl Eollh I let ar olid arPb $p IJE.~1 Ub~ e;~~_ IJU~I UB~ Vitola - ~~ ' id P1 dP ·Ye ~ply rllidt bill a I r114 ynl ~ _ ~ILr~ dd*~~e U~nl nnn 59a.- n~le ImJw ulnl olll nnle 1Qlinr,R, YI ClibPDF - v~~fastio.soni I·I· 4,242,226 on k ~Naul~ctulrd by precipitnting, for oImpie, ntlER SIAIIRTAL, ~D I MmlOll flf pouuium or tedium lipu loluionr dth I solunon of ~sT[FI~QURIR ASO USISC IHE SMIE Iul(oll tuuilion meul with ~ubrclurn~ pylolru md mindpn of the prrdpLc. 'lhc mrul cenlrnl tbr pr~enl inrrmion rcLLcl 10 Oa rlcfi~ 101 1 which on k rhiacd in IhL nunncr, bourvq i pnvu or ligua mcdk Ind rclnro more pinicululy to much mo lo* for lr mljor;ly oflields of use md i i I Lllu mIIcriPI which Eomgnle~ prrdwniPntly ai· dimdl to pldumnine die properties of Ihe thus p aud orb3n in which aivr mcui groups luve km duced rmlerLI owing m the rubsuntiJly und~ncd iarorpnlcd by i Ehohl ru;tion kIween n ulnin~ urucmtr ol$r lignia rbwlce Ind one 01 more mcuI compounds The in· 10 g object of the proenl invention i to provide I vmdoa Jso rrLa so 1 method of rmnuhcllring ~uch novel Ipd improved filler rmrrril which on k used ,BEr I~i~L Fd to I filler ~nd the me 011 I~ltl for Ilrdnl pro~u und liqoid mrdk and which i of eoauiig such bla Mlui~l, she hind comprising I buic subrunee formed from by IcliYUed orbon i 5rsInll3 manl blwt solid InivIled erbon in which mivr mcul group or mrul qb0luMw nmrteirl, such Is chircoIl, bwl EhlTW1 II EOIPPOrmbl me uniformly dispered, wheleuith Lbe mgu durcoll crbon plducd from oil plodueu, ImounI of id mi in aLlion to the rmoul of Ini· coconut cubop r+ which rrrmin lubxpuml to Lhe nted rubon on be rrproductlbly Idjlrd to m opll' dsompmiipn of Iletnic rmlcriJ by pyrolpl uld aU1 vliuc n~mrly ~lkin Ih MpE of iD·X1 pe~ecn~ bY which during Or ifrer the lyrolydr lvve undergone u~ wdbht pdrnbly 1415 percent by wcibh~ It the umr ~nivlling proccu Aelirurd orbon u I porous r~e~ ~D l;w g the mel groups me plnieululr uniformly rLI whose most rhulzrriuie Lura me iu high w· distributed wnthin the Qla rm~rri~l, bsn Lana md luge ~pKifie n~ce Iru, Thus, ~ni· To thi i there i pro~d ul eccordIllce uil h nted cYbon i ao~ I hoswJmous well drbrd m~ invenllon I Br! mlerul r)rch Eoauim I prPdul in ~i~ but tither I mitrure of ~morphon urbon ~od the form of I rmuin olnivzlcd urbon bving i- ~philr crvsrl, the nrios t~rrbemo depending Z1 formly dirp~d therein a Ina one meril ~en from upon rmny fIcIon, a ol rhich ue nor boum, J· ~be group CL Mg, B1. ~ Cu od the umnuon meuls though Ibe choice of lu~in~ rmlnl from which tb~ id produa king formed by chemid reIction k orbon i derived pliyl I dt;isivr pin in lhe propcnia Isrm, on one hind. odonr eompr~ung a lost one O( Ibr IElivired drbon prajuced. wul from id gmup olmedr, md on the other hrnd, Tbrapnul ofsubsllc;s in I filler rmde ofIctivIIed )O iPnic groups chmuully bound to I polyhnorr dniv· euboo ul:er plIee chiefly rhrouSh phpicsl lorptio~ ivr, whercIfrer mid product i pyrolyd ud rd· Ehrmied wlplion rod uulpl; weuonr, II his km nlcd found in ~ respect riot the presence olcwin mculr In ICEO~DO with I preferred emboddnmnr ofthc op the ~krrlPII~J used cUI promote the (BEiMC~ invlDli0h it order 10 provide I pudNLrly uniform lnd ulcli\ily ofthe Q~ilJ process. In lint htrdth ]I nnd rtldily rrproducublr pluiily, Lhe lelintrC eubWI h h~ krn proposed th~t IctivIted cIrbon i imprcB· ,,y bvr ken formed subsunrillly by pyrolysis md mud with dillcrenl mrd compounds, Iharby to ob· dvuion of I cellulose dmnip or I slych dm'n· uia r IcdnEd clibon rhow rurfIcc i pu&lly cov· iw plpllenl ot ~yndail origin tnd teJclfd with mid crnd wilhl deird m~ul ~ompuad. Dne diudvlnuge sruI, lor rinrnple I ~tllulou or lureh dsnvrrivc onp· xil shi physiol iplepiPn of lained cYbon ~O ~pe from oluml lurch or inulin or comprising du· xa mrul eomf~~ad~ however, i thet du interior of mn Mirlurn of such nulunl rd ,ynthrd; stIrtmg the orb3n UMOI k rOched by the liquid, mrulcon· mIIeriJson L k used for Idjwting Ihe propenis of twinF impapltin$ soluoons, since the very tiny po~n the Ictinlcd crbon produced thenlrom. Sujubly, the ii shr nn~l~r u! Ibe cutc~ puuda plmnl Ipnha plyhcrax dmnlvt compria in dd piyhel~u padnriol of the ipnpdn; solution, thereby An· (I derrvIIive, lad prelerIblr the ~nioniF groups of mid dig homogenour imprepnplion of the atbon pni· polyhrIoK dtrivnive tompnu orkllyl groups, wl· clrr impossible Funhrr, this phyriol ilaplepsuon of phonic Idd groups or phosphoric dd groups. PR(m· 11 ~ni*led urbon cwKI ptni~l bloting ollhe pore~ bly mid pelyhsc~e derivivr)a introduced therein a[ thr E~on pmaa tn~in! in m ~pplKibL R· I-3 a~r*l ~uool pc:bwnw unit. duction ofthe lois Iurfir: Iltl Iherml, Further, it i KI The IforemcnIioncd polyhnoa derrvItive Moriei· POI possible 10 control to mY luge cral the mcul nlv, to Idvtnllge from polyhelose or dmvdva ~Fpl;rd to thr eubw pmwle by imarpllicm eilb Ihnmi uhieh hv~ kra acb~linii wil Le id of i aprd to Ilr lotJ oonIlIy 01rhe melll ~nd lr dinribu· bifunctlorul compound, such a rpirhlorohydrin, di· ion ofthe seul on u~d in the urbcn pnicln, u~d chlorohydrn, drepot.ybutnne ese,, opliolully whikl hence Ib i I ri~ Iht the mlul will Igglorerele in I) Ipylyins ionird ndallor to 1 thmdmtntiorul nrl· 'm uadPi~bir rmoMI on the urben pmda, wort nth throuFhpaang porn· SLcq*nl to nne~· An rtinted cubon rmdJ~ nch in meul on br ing this Ihrrdimmliorul network wish meul citrons obuined by p)lol)rinf bent ad ~c~iing the p~0 md subsequently subjecting the ume to pyrol?nlion, 1Fd podua. The ralaad orbon content oflhc Sul there cm k obuined a aivltd e*bon hiving the obuined producl it, xlulltd kne chte#l, i much d0 vtr~ hvoullble combiruson oil wide. cllecllve I~ha· too low, however, lot lr mqPnly Olbl~mnE putpMn. inElurLec od i loll mbrrr Io the lrough·nor of Thr mrOl compounds rminlg dclum phosphises, in the gu or liquid Io be flIlcrcd. The lunlnt nrilcnnl md nImely oltL order olmamid~ oflrom ~9J perecnl the rllml Io which Ihc polyh~nme or dmvllivp by ai~k md hence bone rLrcoll on, in principle k Lrrrol isor Ire erol~·lin~ed is suiuSiy Kltrrd so ski coadd~lrd to comprise I mltm of cdcium rlu which L) mid croll·lin~rd polyhaec or polyhoo* denvIrive is Ire collrd with crbon, obllned in Innubr form Ind his I swelling Iblily in it hs been lewd h InecsivIted eebon ml~rrid attn of 1·10 mllpm. ~,wdhng Ibililv of I·IO C1 hiving md ~~~nliJly uniformly dalributrd Ihrrrin mllpnm king generilly preferred for the mlnu&lur( O Clit; PDF -!::!!::!!::!.f3 StlC.i: 0111 ;i 4,242,~6 3 1 ol~ld oLI 81 CPtnrl lurpa ·Yt I Lr Br! Lvl Lul rl rhieh it ILI Idrnb, Idil ~Dy of 1LI ~I~~ i ladb pnlsred urllhovl d~dd,~ 11111 Br 011 lLw ~ Be LI~~ (0 Be nkla olIttiVIled ~ L~q~CPr~ id WLllIota ~ de ill U'LieIl BL ·6· re, it P"'pa (li CorPrgaby Lr Imounl ol~i·ld~ i i ddilil a de Id ~L~ Ibwr dr Idl I I dpar 8111 alln L lirald, daolyl i a Qir rieL I le atd i IPa onleril aill a Lr de ~)d Be 0111 o ld~~ 16a, IdinYr ai se pidb de rdol Idn V, Cr ollilaa i Be Mele i redu(ed. A lurther Eod· Yr Fe O, Mi Mo rd rb id ~~ LelIL *Id ~~ dYISr ib Edl~ d( 81111 ad & be Iludplol ol Lr dEd* ~ dairrd i ~rslY p~l Qlm i 1L1 de ~et 0( 111 d Bdll proccu. I Y1) d ~1~1 o" 6' ~ L'kl d~~ h a drllcr Wa II~ 01 II pr lila d Be IlltL IUeh I d·il Ild arLe ~OidL I \vieh r~~a h*ndt a~lb: Id d~bl omp La b lound i rca yoa lLl ·YII rll a ~ Y L 10 pnp b irL d Lr ~~ar Pt IYI a Yld aielia Frevnl i I1IP pol~ ~ La ~ pnal i id )rJn ~)n· r la 011 of lhere(ore La pmlad a icolp·r i (he d~aPI BeneuII ce, n v, ct a 6, Si wp ad rd rY~1 ii 8111 IllilILIe LOCic eIIrium nb, Icl a aloiuln be ~il~ eOp)~ I II( one Pt Bt lleub Q phorpLa or ~idr ~lkrr h La Lal Ltd dC Yg Lrl Al al~ ORorIrt LOW'ever, a ~ad~r LP de 81~ b i I pnIeuIs drPle 88 0111 Irrkl Ll 11111 xd~ ~I rla a aC rt i pJo dr & oII lnnu)IT a~Pla. Br mS~ 111 Ln ~ i I qllld! IIEL hi de eliir Gild 10 olY or didcn YI I hn· ~dildOl 01 1 Lelrrm aid n~llld 6( ~lo~ k obuined. &o bone P~~ ~ ·harby 61 ··ldrr dr 8111 o·i· ~od, rYLL* pioab Icral~ btr~ dd i iplolvid srr roIleriJ or I Prr aldill Iid 8rr i*pie aIeium nlB h nblYh iwlCr dl rY hi~l 1 p4arnili b~ll)lo· ~~ p~ a Be upuIlion olcd~~· ~ D~aP ~ ~a~. i hdTPd rd de da:ll problem Ivoided. Lr-ir. j· I End 8~1 IlIrr i I~ihYI ad a Fr lhr PIPP OlobPhbl irErlod* propmir, i) rfTefiive Plbl i ~aad ~ be II d~c-~Y1 be p~ mIt k eoIlrd uili, I praablr or IC doe a Be h~ lLl O( lydle ols pBa d La PIYL I(iL hi eumpie 1 ~I oleelIulox ebRI i IouII i eompIrbon db de Illlla pi dr POL ~oB! d oils cCnld rrb prd~r j Ortr real Ic, IIUEe IlOt 0( 611·1 811 ~1110 81 pll ivalio bit i obUined ~eda ad 11]111 mIierkll Lt 1~00 h* Lae 1 I Bar Ir~d~ li~~ BI Bwq I~ra ap~L agsd. L Inrd, de pea dba cprmaar ·Yrl 0111 i IYL ~6*dl a rpt admium ad Pro Iwrdlr dl ~I~ D br rpir ol 0111 181~ Idr rim Lt let i lhe 0* ~p YI JP~ i 10~00 Iroh h~~ La br Y eomlriaIl Iml ·~p1ll1 Cr riii i CC hoa nl~m~, nk i ndlJrLYI i iuL i LIy llaol L be lorm oil aIl The eIpIIIlIl#n I di ~~d~dlF~IB1~11 FDI1DOI *YEh tAil 1 II lie i lL bb I~~ be oldll n~ i be 8111 ·la LI I~~ BPhy oluellr ~~, nr ·~ ~d~l a lhe invenlion b Imr i de aoL I L tootidered a 11 tall oP4LI L cl Idao(aa tld rrg rl~r eIIeium ii Id· I~~rlpeda pr em', br Lms ofthe ~dp *~4 ·Yel II ·Inb dildbld i dr Lie ~f tr (01 p to Ipl~rd~ I rr ·d dr Iobrunte eomoridnF labod urboh B Ilwnl of II db olLr pm~lo Ipdp I~ 016LOI I G i db 8111 I~~hl llp~d L a Ial U puMI b meLiel a0M.6 Cm· ~r pdde pha I Be rlt rdpe 01 ~l~,r kal U40 peal ~I dlL st Bcd L) that lIrliela a17~ Ippadaldl id I~. Ok loloidr a IIlo Lt mnoved ~I~ dbl rdl~ of Ihe Ioale *~~ lhe reminder Peel lobIeto aD~ a I ·Llbl 4a ld( mi olbr IPle ~~a #9)1, o~lam Be pi lla iewpolrd i IL I~ laiold 0111 aImi i· olll~ aid Ir Ohw eo~)iPI lrIlei! clfB~ ii eIuda fe aYa er 01 arpe i 111 0111 d I ii ilala, tuLr lolYld nrboo CaYe The or a or8rnr iroo Id/or appr lmelll il 01 81a ~ I~ C lnel 8·ll~ Ialteae Bar Ilr hive alsil ILeordinl a Be invenlioll haOr Lve 1111011 I ve]ocilYa hill a ]J on/a rC LL raYaer;or of uulylie rh, rYr~ pna 1111 ~dol of ~ de ·otr dUrielWhieh ii al k Col(h ip ron kl Coddt 1110 lhr rrrl 1010~(1 ad Ol~pl d dl 81 Bar InY, i col~r~b onIY lO Be I rat i dr IObKto IIOLL B Ii *Ip5 de 01 oda oleu(lilode I! OM alP i I d!mr 8r~ Idler ct total C~d eIeeed ore laL olLI O~ ollornul Irnrth. The ampnlure pllldtrar o~al ID~ iereaa a IL ddly ad of Lr eirIrenr ~r IPrlrri~ rm~i~ a 8( invalIoo at Ja Ipprla bl 8rs boo Ipp~dsrt room rlpP k ad br Ola Ir· ltd TpiCA~ill Flra i ~r a ~~# C B Ylt piC a cPllnd aid Bar lrc6~ i I ~· e Imodrm Idlcco Q~r Ih pt moIsllIa or lli· la Pd II ( jd L a rl~d~r Dobdl r~d~ de i Lr rot~ )IrC L p~Pdje D r~la of la· Al rIImpIe ol~ilYt lepl ewnbieIlionr i Le Bur ii dml~L Br 81a ibo~ oTCnl ril Or 0111 I~rbb Bn ed I I ~uJpl erds i*Ldl Cr Cr rlY Rrl ~Lhl lonP! ollnn ed~la ltd Br , ~r B~ ·YFL ladl at I le~rd rC. 10 Dir a $r hi rlIl i i plIilIe a prlarnic Be rl ollL llnitla. R Pa ~r bea p*~, lo· La~iol onbe 8111 mlnhl Il~o~bDI rrd*b~ .j cs a 0111 de Err alrdJ COl~dd~ 01 pdJb Be ~L61 ap k rrpad Ild entd Br r~ pr pdda d Ipk~d ~rke Bi prl eoli· *pYi~rd 81611 p~m, br nlaCr 01 PIP r~a I *bl~il nrp Bmd. Idlll~ due a 6~ ii lhe Y~ alpuias Llily Ydlrl i·&indn b Ibr i Li rl~ Lar i oLlIleed I ~gr iaa i I or ~hlPa al~olr a norr Pde I~ora de bd ldl( *o pr lit ol rdl·e or 8~~ Ir~. PI Br llld e bb a* Be ~eJ pmt L de I O IYr br lhYliCII IdbrpLb A CYIAIIII *il YYr I~nCIC Id~·PeOldlblll~la: roll hon Plm Plde ol #iwd o~r Lores, i (5, YI Ild 21 Yal~ ·~~1 i 110 Lou~n, hive I i W j j 1 _ C I I i; P D ~rJ~~t I`c~-n~iiii~---~- 4,#2,n6 1 6 CY o~l~r ~ I*I * ~ V, CL FC Co, Hi Y d]I aiaivJY rtlulvt daiool (mI IOblCED Co, ~ ~o ad rd tr Ivoldrd. Q i pvliruIIr]y po· Ils~e A rovsioo olorIon I··YI i dr ~ (Prd i Li eoll~~ mil a ii YL! a ild a orbon Loidr db do olns ym i dr II1I · L·~ m~ reb I odIitI *Ycl i yelt i aIimd ~pab rla, i die a IL o~ I" i YC ~~alaaa 0 orlialutullaioIlran 1 dll ~~ bit i Ib arrl FIQ~ ad/or Q· lidlly 1Ya~ ~ Gconlarl ohhl Bwr ~d~ ooool i I 1~1 rl Ihl the ~lu olh ad/or i *ioYlr hi D pt Ly dCr prPa 041611. Co prarnl i Iid Idslhlld I lad o101 Q· Pr Ola rod ~611p $r arad· a ia oral Tbr Fr I11 Cr *r fonveoionlIy ieaporIrd bo J br ~lardl pYle It Id mdail Lmb i oIidr a ~Y~de lorm. aIir a olhs IIYdt *b~uneo inI Eqid an· I h be llrlOl pi u~ldll 1841 Ildl Iro~ dtb i ~ip rC i 11 rt~rmFL· $( il· IrvieI 1 rombinrd ~lat ad d~~ h lor ~ ~ ~ i dro lurilYinI Ia or Tqd. ;jd odor or L IJeard a Pr invenlion JI t~la 0 I 1~6~ ~arlba*- LI Y Iou W~Rn Ly ilh cn~l ~r~ dlrP1 I ii dr Ilorrdrmikd 814 PIIY. IC amid i rll i aid 131~ eapdlb a lal one dL ~~! bld~ by dr Ladl ·roaa~pYII Il Irol Cr ~ i', CI fr 6. K1 #o Id lb rYh IL ~1~ oDr Id do 810 II Ig Q YL ~ AI, IeMjodfr ~oP~ r lPr r of br Id Q YL Co ad thr mrYol IrPk ad ·lic lolp ~d· 81 ad Al. oUy bood a I ~1~1 drdP~ts to ooId to for rhf Ilp of ~lD~l(lr 1 Orr Irrhl oLaiony t~ uid PCI ObL ·L~dl 61 ~· loiubIr bl P~I( Y~ ad E~r IJh IrPI d· bor prduol k q·d p)rDIyxd Ild rolivmd p P or prflrnIIv drrivfd boP I a~ Itn lrorn LI Isll gR I IJ d ~d orIoo hil I~d (aO Q, WI ad Zr If road aB I poIyhrlov d6r· dd Foup friloPJY dk~ dneio. Ar I ~I i~ It LinE ~LnYr ad I ddn ·L ·Ycb i nuY BI eid ~II~ Yri* bbC h roovr- Oli·d! Iddrd L a air rooI ~I Be plrl! ieldl Id ~ldr, 1·r~ or idk ad Ids, da lroen! i 6r YY ba Ba ~ld i r la Immb bca i hl~l~~ hp $r Pb~r~ ddr~ ~ IboUI W oafor by ~II in I c~~ldk unwlu d mmII, liP~I IIw! ADOII doe 01~1 duivIliver ·YB a L led ]CU ~nl bl ·deh ar~, paQaYI ~j Id · LI InbPldly Om moml Iofordinf r be i· ir per L·r lit Al~~lg·b Llr i wd a ador a br ocrbl~ L! ry d el~e ~I~ dde PoIyIoaf dcd*drr;cl a I ~k~l~ db mdl~ alJa Jim or plml uII of ~~ rivItive *hr djdr polp eolph cIrbonvl 1 mrlhyI ErIluIoe, Cm*dm of )LYe IdP a n, golp, *$Ye dd Corp a p~lode ~ Ye aid a ~~ ·liF ~C ~ oIIolae ad ~ CIP lulphurir Idd d~dsdu plcd~loc ~I Fd~~e i hYb, dr IYr lp63 i prodoord i lal+! dr Ib* olfnrioord dedad* a k qY ~L BP be iaoial ad tar Idpoya prdla BI ~~~~ surrh a LPP YI O'r i ~cl 61 rc~ol Cdz oIuiod by U n, rPI odolr uad i oajooaia r dr n, rredr ~*a I lal J: ad a aid PoI!'hrIoa b~ll ddllllll~ IOPdhllO It j*ld· Iddvr i pdr~d Idp a 61f p~b~ ad a rilYI pre i Lr bm ol;ml nla tYd Idad A ~~~ binder, prhY! i I Ihd*~ do~d L ·hYr io rra ad ·~e~ me Lad i be mJ q~dt *EI a r n 10 ~~I L~ ~CI Eqdl oLa Ela~dh a rhr pldr or nd dld~ ry be ddd 0 id ~o~~op pda or oa ~1 9 dvs rlm~b Lr ndol p~l~, 6~1611 for · ~~, tharbv to Y yd lraloIIirI p'~a dr IIIl ~ i lreoiliulrd *I dlo I~llr~l a ad/or a iaoad p~ld laDh d lhr a~ b Idrll I IloU1 prajiPdll IIrol, a i ddd a hlf dr dair(d dg ·~Pler ora~ ~ Pair ladla A ladada rdlnll a L obuinrd by ail a de L Cnd a lie dairfd lair alll· CbLn derivIliva OdC~II bP I pkhl 4 dOL I Lb b la LII Dir Ilo~lYlp o ~rral I, a I ~~ol d~~a rba 11 La pg~iY ~C 441 pdla ad ~ rIIapIf, ii ~nt Idd. ii d~ Id oil YLPDI~ FDlr·b ·Cb I qC Pr Yd Pair produrt i 0a pyroIyxd i I m~ yppJ~~ 0 fonn I Baedo·oPPI Iri h~ Is boa oaI i IL Iber dol~lP Br o16· ii bmllCloil r~· n( p(~ ~ta aJ ~j p dos ~b ~~ IL p~lyl i r~~ YI r· be id 3·L lRll~ d8e pda to, dwvlI Pla~· M Imd ael Ihl de l!roIyxd prdool i Ya d~ (lal a dr ~l~iYI toapo i kior ~Ye a Ipnl p~· Lid! r It pyrolyed Tdlo a f~ dr de IroirI rolrriJ ad 01 dire dcm~lb k rubjard a I Ila~t·l IaivmioI ~~lr br Ll,cl lLI dr ~illd amsiJ i ·Pnak a~~ ~~ at Iw ol~~ Coddr okrined i laooL (111 dlh opm ~ra arad~l I~He lejrrlivr popda e· L bhird by FI· laa I~r a n~, rlar*ib II yllta al # ii rhr IPlla II~IIII aid PFS~, ·II I Iar I PI) 6040ion ~ bl eumoIr, (1~1 II. ~··YL 01 mlpn~~ ta~PC br ouopIr dB ~ lallCIPII porn rr aIaaod Ibrdjb I hpr olPlIuiov SrDr. Aclivf PYr rldd *· iPa i JI rlar~ orb31 lormrd b 01 o~ Fordins I dl ar1103 lip k IllhP·~ i rb~ t· 111~ ~~ col~iLI I~d f*C· SriObly, bp drr ril dr bloril ruolh: i · MAWI1E I Lo~ d~·d* wirb 1 I·dSII JT~ 1 *la of GD IVy~. 1 Iloll~4lplmrl~lPI d~~llPIJ~ F· be ~IIIBarl pi I 801 muil rYcl ii relluloK ~ Idlhd ~d 103 II or 1 Jt qlsr I"Ydl *idt Lr Imlt ahoo lao~, d· alrLI oI CICh I11 L drop( d fonrenlrllrd nsQ dll adoa la lKd L I lall) rh Ibl Lr Ilar I) *Lb~La Br Ilna ~ nrRd br I Lo~ r rooro ; olC1 pmt ir Iid yd*l i I b I~odm~b I npal· a." 011 br i holn I I npaan dlB O pm b ·elh, ai~YI r lot I~mimddl Il C, Pr *~apl p~r~ Ba bnld nl s~d ad pru I! a~~. nr Im xllbalad Err lip 9· ~*~~ Ild *IPld *~~ XQO od of H!O, *Lnb i . b L ClibPDF - v~~fastio.soni ~·;;;i· 2~CJP~i~~ --- ' rvY ::_LL' ·1t. 4,242,226 1 8 Int! it YU tr·slmed. 'fhe product wa then dried in I crP~-linU with die lid oil bilunaiond compound to Ipltya~ing apparatur, whereafter it wrU pyrOlyxd from I PorWI (hr~dimaiarull ndrWt ad activated in a ailtoFm atmolohere. by prcgra· 6. A bla mnaiJ aKordinl to clim I, wherrin that :~ flullr nidng m I~m~nlure to 110' C id aw·lio~rd pol~Klow or polyhuoK derivative 1 ha I pJbbilily in water of I-X1 mi/gram. ~#PtE~ 1, A Pur material according to Jlirm 1 or 1. IEYI I oldrid ooP·lin~~d chronuIogrnphie gd wburin id product Eonuin1 from about I~~S pcl· having 1 sin rile in dry Iule of between 0·I and 0.75 cent by weight ofI metal xlMed from mid group of mm and a tnaaimum. Iwdllbilily of I mVFnm wa mak Jum;ed by curfully itimng the are in 7#) mi ofd~ to I. A fiber material according to elinu la Z tilled n~u II I temperature 01]0' C., whereafter the wherrin mid product contaIRI IIieattabout 10 peroent gel u~ II to Impd for I ho*r. ~he arplw uUcl by weight Ca (abcut I#lml) uU then dlunard lad 10~ olcium 9, A Ler material aerordiag to claim II, rhsein the chloride solution wat added in at amount mnnpnd· product Eontanl Ca in an amount olat iuu II percent .:a i~C'o lhruMnnt oldc;lnlcrcd nltr.nK Id Illr~lis II by ~i~h. '" rI with the added uldum chloride ~oLion wa Ibtn 10. A 8llcr material according to dim & whndn niad allully Iw 1 hnus and hm uh to ILth far uid PTddYI FOIIUibl 1( lcyt one of h ad tu in a ou hOYI. Thl arpiur orlhe added airion vnl drua quantity oflt lrert onr·lm~h olthe Oconal Imb u'b~nhrr the dimenlLd gel pmicln wn~ ii. A 61ClplmPI ~erordin~ to c~3u 1 or I 10 rhncin It leat 10 percent b~ weight of the amount of uuhcd. P~clcd and Cried, fint alampralurr of II' C for 10 houn and Crullg II I temperature of BS' C for metal praenr in uid product compri~c~ II lun one of 1 further 10 haun. The gd gnia were Ibm puued de meull tu, Ti, Y, Cr, Fr, Co, h'i llo and Pd, ad directly to i Biiehrxrfunnd and imlllydr;rd a i pr& the remainder compri,o II Irut me ofthe meu~ Cr, lurrkoalunbienr pmuA a I temperature o!Y1' C Me~ Ba and Al, for onr how. Thr Erun ion F~ Cund to be rQIII· II P A Let material according to Lairs 1 ar L Wy uneh~nrl,lbil the Iv~il8ilily had I~lcn ham lvberein the md dirpmcd iadn i d~rd i~ IbF dr oneY jmllgnn: to Ihoul 1 mllInm n( ~lod Iroup cpnriainS olCr Ug and ZI. .g uct compiing the gel lrainl wa then p*olyKC md 13, A 6hrr materii according to elaimt 1 or L in activated in I airo~m Ilmqhrr~ by p~egmrisly 10 granular form 3 ruuog h temaeralurr to Ipplo~imally 110' C Ia. I 61ur macrid o;ardloe to c~i~n 13 uihmin fhe 81111 aarili Iccatdine ~a Ihl;nr~mion un be the IMuln are a~rd sil a pamu~ic III umiyrmr tued on iii own, Of in nn(un ~lh other fdLI1 material, Pr coming. rC in mitnur with at iam ftller, rueh at ccliulor, II, Thr filter material according to olaimI in cDmbi· eellulolr derivative, or diatomaceour mt;h, nte pol~· ]I onion with an tnert Birr. huwr derivative, to which meul #tionr are eLmi· , 16. A ftlter ronuuuaf I IJn cataLl according to erllg bound, may be formed from polyhuo~ during dlim 1. th ~jMlioniDn rhfrmllo I pol?hua~r derivaivt. 11, A method of mulul~uME 1 Par material for Tot invnbon ir MII Ideld IO Ihl Blrdncnkd ienng gaeouI or liquid media cPmpdril dr Igcl rmbolimra~ but can be 8R~ihed Within die ~p olq reacting csrionroll~ leaat Dne melJ xlcard from the the inventive Foneept a dbcloKd In de [0llowiall group Eonrirting olQ big Ba Al Cu and die IMi· Ijon mLdr with aFionuc trWPI chemically bound ma '": lubluncl mn~b~inl rnrr.linit! pit pol~nox drk· .* II Ba rrmtri3 for filminl prrapt or licluid m~· live. xpPnung lr ranjon prDjuel: and pyrPipiny 64 compwnl a product in lr Lrm pi a nuau of 1] and arti*linI the rnctirm produn to Iprm I rrmru of activated carbon hvinS uni~rmll' dUPIT*d therdn at Irav~ld carbon bavinI dte ncul uPilormiy dhpmd ]rSt one meul xlmcd from the group eo~uininl of therein. Ca hlC. 85 11 Cu and the mnrilioa m*lr, Illd plOd· 11, A method according to Lint II, oherrin crllu· UFI lallPb by ehaninl rcaerimt bawbn aiopl ol~l IoK 01 lurch co~priK de ltudng rmlerLI C id kut one meUI from nid group of mcub and uuonie 10 polyhrlwe derivattve. pouC ehcmicalIy bound Ia a wbnma wluinine n· 19. A method according to dim II or 18, u'hnein .i ` tcotilly ola palyLolr derivative followed by prmly· the ~nion~ group, chemically bound to id polybox it and actintion ofuid product, Irrirsiv~ are carbolyl Iraup, lulp~o~ and Cur ct I A filter mllmJ according to dkm 1, Fhrrdn the or phoiphori: add eroup~ .'j ~ ai\nlld carbon in uiC pmdue~ anlirllll irom Ihe 1J 20. A method aFoldinl ro de! II of II. u~btrrin .1 pppl)ulion and leliaaon all ctllulorr daivativr or the plyhca derivllive ronumr horn I·] metal ios -j nucb dmain which ha been reacted mi id clli· pr huoK unit. ;3 ·L 11. A arthod rrPdm~ to dwru 11 or II, Fharin J. A Rar material according to claim 1, or:, wharin the polyhmr dmval~t onlLa from I pol~mPx dir anionic group chrmiully bound to ud polyhox #I or a polghaou dttaivr F~i~h ha been crPII·linll der;ndvt we e~lbon~l group, dphonl; rod groups with the lid of I bi(umiool compound to form 1 po orphaphoncddfmuy mur Ihrrraimmaod nnworl-. a A bler matertal according to FYmI 1 or T, E. A method according to dim 11. rhaein tro~ wherrin id poi!lleaoK derivative ha iouoduFcd Iinked polyhnac or ero~r·linLd polyboK dedve therein from i-3 metal r:lionl per boK unit, 6) lie ha I ~rrlhbCly in water offrom I·IO mllgrun, I. A 8ltr material IFEPrdmg to clum, 1 or Z It. A method aetordlaE to rliml D or 18, ulhtrrin *hcrcin mid polyhmoK derivative oligin~ln from I ~ppmlimsri~ Ibllptaal bg.osh~ ollg metalh L polvbelor or a derivative thereof which hu btm introduced into id product. O f Clit; PDF - i:!!::!!::!:f3 Stlc'~iTii i. ... ,.1L 1242226 9 10 U. A ~nahod lcrad$I !o ~l~i~pl II or ]k whnrin ePmprio II h oar of Ow mrJ Ca, f~ V, e~, Fs okium oliom la lurP h n pwnly Do thu lr b ~i Mo lad pd, Ind Ibr rermindrr compri~n nI uaoun~ oIO proml in aid p~oducl ii II Iclu Ihwl 10 lau par pi Ihr mrta8 G MC pr md Al. prcrm by unigh~ 21. h m~ad ~ordiag lo oiniar 11 or II, urhmin U. A ~Kdud lrootdiaI to J~ia~ Id ~uhadn Ik ~ ~claial wioa~ wmpriu at kul oar o(Lhe paull G, pradul cowia O i a uawnl ol~l Icol ]I prsnl Hludt. bi~l ID. A sabod lroordiaI Io dirm II or II, lunbn r A ~tho~ rcoldiol to rlnhn 1(, eompiaing Jlo Ipdng nI lrnrronr olFe rad Cuu~iolu in an Mwn~ Eompci~n~ JK urp 0( gMuLLinll raid produn prior to lo Ilu~ I~r Moaar pmcat 10 uid produet k u ~11 10 pyrd~h~ndlcdnt~h on~·Emb olthr e~so~urnl 10 A mnhod neFwdinl oa eYm 29 funln eompri~ II, A mahed lawdinl to elinu II or III, shmin inItbr ~P olonnlinI Ihr gnnuln vlith r plmwble or lid PdOlll Ur ILlmrd 10 t)UI It 1EUI 10 P~FCIII by ImiPLamtlbk Po~inl mbwqPcn~ Io pyrolrir rd~h~ of lhr Imwn~ olmeul prwnl in aid pmduet II I ··o 'cn N Clit; PDF -!::!!::!!::!.f3 StlC.i: 0111