7 U s/ RESEARCH LABURATORY IRESEARCU & DEVELOPMENT DEPT. November 24, 1958. EVALUATION OF "DIPLOMAT" CIGARETTES Samples of VDIplomat@ cigarettes were given the laboratory by Dr. George F. Wright during his visit on October 31, 1958. Theme are 85 mm. plain and oval cigarettes, made by the North American Cigarette Manufacturers Inc,, and are advertised an OThe Safer Cigarette". It to claimed that the tobacco h" been treated wto, reduce the harmful physiological effects of nicotine" and to produce a lower temperature of combustion. In view of these claims it was thought desirable to examine IDIplomat* cigarettes for whole tar and nicotine content of the smoke, nicotine content of the tobacco, amok@ temperature, and /Owl' temperature of combustion. The results of this examination are outlined belows THE TAR AND NIUUTINE CONTENTS OF THE SMOYX-, Analysis No. A-154 REFERENCEt- Modified Foster D. Snell Procedure for the Determination of Whole Tar and Nicotine in Smoke, Due to an insufficient number of cigarettes only three whole tar and nicotine determinations were made on the smoke by a Modified Foster D. Snell Procedure. I For the sake of brevity the pertinent Information on thene, cigarettes has been summarized belowt- 1) Average weight of 134 cigarettes at 12.0,U" moisture - 1069 mg. 2) Weight range employed for selection of cl rettes for whole tar and nicotine determinations - 1070 * On mg. (unusually wide due to sample limitations) 3) Average pros Sure drop of 114 cigarettes (for an air flow of 1050 cc/min.) - 3.5 Inches of wator. Pressure Drop Range 1.3 - 5@.8 inches of water. 4) Average pressure drop for 60 cigarettes employed for whole tar and nicotine determinations - 3.4 Inches or watere Pressure Drop Range - 2.0 - 5.1 inches of water. 5) Average weight'of 85 imm. cigarette papers - 5Q.64 mg. 6) Nicotine content of "Diplomat" tobacco - 1-57% (Average from individual results of 1.56% - 1.58%) 7) Avaraea porosity of 8 cigarette papers - 100.2 cc/min. Porosity Range - 94.4 - 104.0 n. 6) Th cigarettes were smoked to 23 butt lengths under standard The cigars (one 35 cc. Puff/min.) C=) CN BATCo document for Province of British Columbia 21 April 1999 2 The smoke analysis results have been records& In the accompanying table. REMARKBi- The whole tar and nicotine contents of the smoke as well an the nicotine content of the tobacco from Diplomat cigarettes were found to be higher than anticipated In view of their advertisement an $the safer cigarette*. In fact, the smoke from those cigarettes contains as great a percentage of whole tar and nicotine as is contained by the smoke from 80 mm. Pall Mall plain and cigarettes (approximately 4o4% and 32A respectively). Hance It would appear tbALt their advertisement Is grossly misleading from the point of view of tar and nicotine contents of smoke. It is possible that the tobacco has been treated In some manner that might Imply the statement "The safer cigarette". The nicotine content of the IDiplomat* tobacco is also fairly similar to a typical value for the Pall Mall blend, The rather wide variation In the tar and nicotlne results may be attributed to the unusual variability of these "DiplomatF cigarettes with respect to both WelFht and pressure drop. It 18 noteworthy that two of the six packages opened by the laboratory contained only nineteen cluarettes. COMBUSTION TEMPERATURE The combustion temperature of "D cigarettes was meas- ured by our standard method, that Is, durin puffing at the rate of one puff per minute, 35 ml- volwoe, 2 second duration. An usual, the thermocouple wires were Inserted at a distance of 15 mm. from the lighted end, perpendicular to the long axis of the cigarette, and In the case of this oval cigarette, along the minor axis of the cross-section. Because of the small number of cigar- ettes available, no selection by WOiEht was possible. The average of ton determinations gave a combustion temperature of 8570C., a value somewhat lower than that for 'Player la Mild* (879 In order to ascertain whether this apparent reduction in temperature is a function of the oval Shape or of the tobacco used in the cigarette, similar measurements were made on vVirginia Ovals no yielding a result of Al. (*C. There remained the possibility that oval cigarettes did, In foot, burn at a temperature similar to that of round cigarettes, and that we were recording an erroneously low value, due to excessive conduction of heat along the thermocouple wires. Accordingly, another series of experiments was performed with Virginia Ovals In which the thermocouple wires were Inserted along the major axis of the cigarette cross-section. This was expected to reduce the amount of conduction along the wire and henoo to give a better approximation to the true combustion temperature. C:> C=> cr% BATCo document for Province of British Columbia 21 April 1999 3 'Cho result of tUs experiment was 8530C. Since all three temperature values lie in a range of WC It can bo concluded first, that the measurements give a valid estimate of the temperature of combustion or oval cigarettes secondly, that tits temperature Is significantly lower than that for a round cigarette; and tnirdly, that "Diplonat" cigarettes do not exhibit a lower temperature of combustion than conventional Cigarettes of oval shape. ;MOKE TKMVRATURZ Temperatures in the smoke of $Diplomat$ cigarettes were 4stermined in the usual way. Heaauramenta were made with the thermojunction placed directly behind the cigarette at a distance Df I mm. from tao end and normal smoking conditions were observed. Although no selection of the cigarettes was possible, the results were reproducible and the determination was made an a sample of five cigarettes instead of the usual eight. The results are alhown on tt,.c accomranyine., graph, and the corresponding curve for wBuckinChaml is ahown as a reference. rho difference in the base lines is due to a difference in room temperature at the time the exparimonts were performed. It should be noted that the butt length refers to the lanL9.,th at the b:SinninE of a puff and that the puff consumes approximately mm. of tobacco. ,,M -TORY RESEACA CCM/BJS/FF BATCo document for Province of BritiSh Columbia 21 April 1999 0 0 CL 0 Cl# SMOKE ANALYSIS RESULTS r+ 8! -brand or Average weiFlit -'Qnole Tar -0 -of rn- a Cigarette in mr,. Wt. of Tobacco -vt. of' Tobuccc he 0 Uletj 0 Smolced/CiEt.ln ked/Cift.ir -MO Ms. (I"Olsture irp. (1101sture @'ree bazis) @ree basis) 0 _% Diplomat 1069 6 28 9 55 642-4 2.1 .328 heold Nov-4/58 4 29:0 @:51 6L2.4 2,0 .308 637.7 2u.3 L.12 @L@ - 9 1.6 .276 43-6 _-_0 7.73-9 12. 7 7 7 T013@ 0 0 3 cr co to to I 00 I 0 0 CL reo ,bo 15GI CD 0 -% r+ cr BuckIngban 80 CD Dlplpnat to 80 70 60 so 0 30 20 10 0 BUTT IMOTH R9 I z loo I > 1APH OF 3MOKE TEMPERATURE VS BUTT LENGTH. -i 1 2 3 4 0 CL 0 1. Consulate ncrms' Ws li 2. ConsuluteJ,2 I/Z it Pall mall K.S. PI&I Rcthmanm K,S, IlaIr '160 lb. M-' 140 0 120 0 0 E, 100 cr 60 CD CD CD 80 75 70 65 60 55 5 5 0 45 4 0 3 5 3 0 2 5 20 1 5 1 0 BUrr UWGTH mm. 6 0 0 @1- !tl @1-1- TABIZ II TRO IN THE SMOKE OF SU CCMIVE PUFFS IN OVER WEIGHT CIGARETTES AND CCM A TM NORMAL WEIGHT CIGARETTES. otairans K.31 Pan ample consulate Consulate R Hall X,S, Puff N Plain Plain 1% No, 1170 L.11 1094 3-0 1200 1.5 1090 20 1 77.5 78 76 78.5 2 77.5 78 76 78.5; 77.5 78 76 78.5 77.5 78 76 78.5 5 77.5 78 76 78.5 6 77 - 5 78 76 78.5 7 77.5 8 76 78.5 8 77.5 @2 76 82 9 78 116 76.5 90 10 94 158 81 118 11 150 19 102 174 12 198 191 147 198 13 176 40 K, CD 011 6 BATCo document for Province of British Columbia 21 April 1999