A PhIVA7Z kn COGFJE0.'TIA.L Jwvav-~~:'C -f'7 V,An Septenber 1~4,P TUjpERATLiF.E MLASLpM*,NTs ON CIGAF=ES JITJi HIGH PAOCL%4G DaiSITY AhD AXIAL ChANNML INIMODUCTION According to U.K. Patent No. 1,086,44,3 granted to Messrs J.A.E. Bell, J.D. Jones and D.H. Laing, it in declared that, "It Is an object of this invention to provide a cigarette wherein the tobacco Is more tightly packed tawi ,eietofore thereby creating a lower idle tenperature. It is an ob.'-ect of the Invention to provide a cigarette having &r, idle temperature of about 5300C and an average maximum temperature of about 6650C ...... much lower than those of a conventional cigarette. By average maximum temperature witn the invention, we mean the average temperature of the hottest part of the combustion zone in the densely packed tobacco in the inventive cigarette during a number of puffs". (Column 4, lines 85 - 108). Cigarettes manufactured by I.T. Co. Canada with packing densities up to 1.5 times normal were subaitted to Messrs Bell, Jones and Laing for modification according; to their patent. An axial cmvuriei v;az r--roduced In tnese ciSarettes with m,. 0.06" tangsten probe heated to 430 0C. Sanples of ti,ese modified cigarettes, together with the unmodified control, have been examined at F. & D.E. Temperatures during the puff and during the smoulder immediately before the beginning of the puff were determined. The results obtained to date are discussed in this note; It is not anticipated that the ex,jeriments still under ..-ay will alter the conclusion. that the claim made by Messrs Bell, Jones and La-Ing cannot be substantiated. EXYMI)MEWAL WrAILS Eight samples of cigarettes were received; these consi3ted of two groups BATCo document for Province of British Columbia 5 November 1999 -2- of cigarette rods with added high and low efficiency acetate filters. Initially It was decided to restrict measurements to the cigarettes with the kagn efficiency acetate filter as it was anticipated that the filter would have little, if any, effect upon the temperatures of the tobacco rod. Cigarettes were conditioned L98% R.H., 680F) and selected on the basis of raean weight and pressure drop. Temperature measurements were carried out using three PVI)% Rh-Pt thermocouples, in tandem, with 4 m between adjacent thermocouples. Measurements were made In duplicate with the thermocouples placed on the central ax1s and at radial distances of 1.5 and 3.0 cra from the central axis. Swulder temperatures were measured 1 second before the beginning of a puff, and puff temperatures 1.5 second after the beginning of tke puff (see R..& D.E. Report Mos. 219~-F, 287-F and 331-F) - Visual inspection of cigarettes which had been quartered showed that for most of the ci&Lrettes txamined the channel was not on the axis of the cigarette. Uamination, of th~ butts of cigarettes used for temperature meavureasento also showed this effect. (A photograph of "ations of a typical cigarette are given in the Appendix.) From this evidence It 13 concluded that it is unlikely that the centrally placed thermocouples were actually within the channel for many of the determinations. Cigarettes were smoked on a B-A.T., restricted, arnking, engine at one puff per minute, eaen puff of 35 ml and 2 seconds duration. with increased packJng density the puff duration increased slightly. The temperatures measured were plotted argainst the distance of the thermocouples from the paper bum 4 seconds after the start of the puff and the graphs used to give values fori Un BATCo document for Province of British Columbia 5 November 1999 I - The mean maximum temperature. 2. Th emaximum temperature recorded. 3. The distance between 7000C contours. 4. The distance bet,,een 4000C contours. 5. The position of hottest part.of the coal from, paper burn edge. 6. The distance the 2000C, 4000C and 700*C contours moved between the smoulder temperature measurement and puff temperature measurement, i.e. 1 second smoulder plus 1-1 second puff (eff'ectively 11 second puff). Vc distance between 200 C and 7000C contours at the butt end for both puff and smoulder. Temperature contours were also plotted to give the general picture of the puff and smoulder temperature profiles. The results are given as an Appendix (Table 1). The most significant effect is the increase in mean maximum temperature with packing density. Plots of these temperatures -gainst packtrg density are linear, with the exception of the smoulder temperature measured at _3.0 mm from the axis (FIXure 1) . Temperature measurements an the unmodified cigarettes with different packing densities, confirmed this observation (see Appendix, Table 2, Figure 2) although the increases in puff temperatures were not as large as those measurement& for the modified cigarettes. Only small differences were noted in the "distances between like- contours" and, allowing for the rather inexact nature of these measurements (the paper burn is the reference mark) these differences are probably not significant. From the temperature profiles the volu of the coal at a temperature &-eater than 700 0C is least for the unmodified control cigarette, for both puff and smoulder. The cigarettes with the highest packing density CD 4" U1 BATCo document for Province of British Columbia 5 November 1999 -4- have a more L&rrel shaped" profile than that of the con4--ol and tnose with interr.leaiate pacrcing dzii3itles have more pointed hot zones. Mie puff te--;.e2rature prof-'le for T1,e cigarette willi packiri; dersi%, 1 .4 nornal Is Literesting because, towards- the butt end, tne lower temperat;.re conta6rs, e.g. 200 0C, extend down the axis of the cigarette. This is prohobly tae or.1) case where the thermocouples were actually in the channel and t.-wrc higher temperatures measured are the reLrult of the hot gazes stree-ig da;m the channel. From the srzulder rates of the cigarettes, and the distances between the 2000 C &-id 110C0C conto;;rs or. um axis, it may be concluded that the rate of herating o" the tobacco during smoulder dacreases by 11;Z1.'- as We pr.rki,-..:- density izoreasea by 505. Generally, tne rate of heating Is inversely propert-lonal to the packing der.3ity. Measurements carried out with a puff frequency of .3 ;uffs per minute showed "t the dirrearences between puff and smokilder temperatures are not very great as, ;;resumably, there is Insufficient time between puffs for a steady &raoulder sizate to be reached. (see Appendix. Table 3). Compared to 1 puff per -'-,-.,te, the hot region of the coal (above 400 0C) is longer at t~ie IUCher puff frequency. Tem~,erature measuremienza made with a 25 al puff, tazzw. once per -An-te, indicate that the cw-b;2stion temperatures at this puff valume are slightly lower than those obtained with a 35 ml puff (see Appendix, Table 4). Only the unz-odified contral cigarette and the modified cigarette with the highest packing density were u3ed and Uie temperatures measured for the latter cigarette were higher, as found for the 35 ml puff. Thus, it appears that the temperature changes noted in the modified cigarettes are probably attributable to the Increase, In packing density BATCo document for Province of British Columbia 5 November 1999 wid nc-. to Lhe pr*senca of tic axIal. aharnel. Further, xic evidence hao beeii f3=d to wupport U,e clairas of Messra BAI, Jones and LaixE, as all ci,sar-at'Las ew-ined wit-'. a caannal have had hl&l-,er puff and s-.io'Ader temperatures t4w, tbe unmodirled con-trol ciWettas. Q) BATCo document for Province of BritiSh Columbia 5 November 1999 AFMIDD: CIGARE-ITIL SPECIFICATIONS Code Xt.~mber PackiaF Denalty RL 268 F.L 2:~EA Kish F.E. Acetate Filter RL 2Ea RL 2c\~c xl-5 TtL Z,~~ xi RL 2-S2E x-1 .3 Low F.E. Acetate Filter RL 2~,!"17 xl .4 RL 22~;~' X1.5 Samples FIL 268 and RL 2-3D had no axial chwriel. CIZ&rettes selected to mi= weight and pressure drop. Weight Pressure Drop (JZ/civ.) (cm W.G.) RL 268 1.12-1.16 16.3-lT.7 RL 2bm 1.36-1.42 14 . 16. 1 RL 268B 1.46-1-52 1 E- - 16" .7 RL 268C i._ri:-1.62 17.5-19.0 Cigarettes not examined for combustion temporature. Mean Weight Yean Pressure Droz (0./cix) (cc W.O.) RL 2-:&r 1.10- 112.9 RL 26BE 1.42 14.1 RL 2:ZF 1.50 12.0 RL 26W 1.6o 14.2 Q;I 00 BATCo document for Province of British Columbia 5 November 1999 Cross sections cut from sam cigarette showing the v&rlable position of C-D the channel. This cigarette had been selected for temperature masurements but was not used. BATCo document for Province of British Columbia 5 November 1999 Pu TE ff MPI: pe MAT r m TAM UX in A E ute I WA , G VRM mi Ws purr o e o. h o moco ple e n M ' p 'i 7 A i * Pu e tw C ff to. ** on * n to . i 1 is 4 t 1 : a "* C ce *n on - - A pr of x " t : . a r rn M a T a xi e n . m- I' pi a T Imu eCoj I 7 O is st RC t ~ Co nc *n nt Sm e ur ou . ld 4 er D 0 B 0 s t C an o wCo e to n s p o Co r f al xi Hot fr a t& om o st Pa i Pa pe t rt r a W ee of rc 1 KL i 2 tZ 1 8 15 8 25 6 11 7 7 60 760 4 9 .5 8 2 T 9D 8 10 6. 5 12 6 T IO 745 2 10 7 7 30 7 30 2 7 .5 4 6 00 62o - 6 .5 5 8 RL 2 68A 1 8 .30 8 55 7. 5 1 1 .5 a 7 75 8 15 6 .5 12 .5 1 2 8 40 8 65 6 1 1 5 7. 30 7 55 3 .0 9 .5 6 3 7 60 8 25 3. 5 9 2 6 30 6 45 8 5 10 HL 2 68D 1 8 75 1 0 60 9. 5 1 2. 5 9 8 00 8 15 6 .5 11 .0 2 7 95 8 15 6. 5 1 2 6 7 35 7 40 4 .5 11. 0 7 3 7 80 8 10 2 7 2 5 6o 6 05 - 6. 5 4 RL 2 6W 1 8 95 9 05 6. 5 1 1 7 7 90 8 o5 4 .5 11 8 2 8 10 8 10 7 1 2 6 7 50 7 6o 5 .0 11 7 3 7 70 8 15 1 . 5 6. 5 2 55 5 5 90 7 4 Dl Axi 2 -t s 0 anas o *C cCon 1 g to r ru %t e o Mov In c es 1. B& 5 7 6 c 0 - k on sea *C ) D I V C C o e & nto Ba 70 ur t -g- 0 C D C = nto . C & ur (d Bo 70 On ) tgo 0 C Axi o s n 1 mo 1 e r a e l Di e st (t) f n r ce ( x r i C 100 te ng to -C o r 7 pe f o 0 r o e a c n) RL 2U 8 1 .6 1. 7 9 .2 4. 4 5 .0 3. 94 RL 3 2 .9 68D 6 1 .26 3. 98 RL 26 8A 1 .3 1. 1 2 .1 3. 6 4 .4 3. 10 RL 3 2 .0 68s 2 1 .42 3. 1 RL 26 a8 3 .0 1. 8 2. 1 5. 5 4 .5 2. 98 RL 2 2 .9 68v 3 1. 51 2. 98 RL 2o SC 0 .4 0. 8 1. 7 3. 7 5 *1 .0 ,aw f i ie 2. no 71 y a RL 2 et 2 .6 at 68a 5 e f lt 1. er. 84 o n i ar t 2. te 72 ro . 7 hormooouple I - Central axis 2 - 1.5 me from -1. 3 - 3.0 - from ..I. OqzzqpOOj 0 0 CL 0 (D T -1 0 CD 0 h UO U) 0 0 E" 3 Cr E" 01 z 0 < (D 3 Cr (D "1 C. mo. H-i-w ., " ei Tle-pi C j RL 2o8 81:) 825 KL Wb& 835 860 RL 2.EM 855 855 RL 2L,8C 84o 850 TABU 2 AUAL TWPIRATURE HUAStMEMENT3 CN UNWDIFIED CIOARLTrEj 1 puff per minute, 35 vA puff Puff Smou lder UL.tan.. Distance Approximate Distwir M..n e. 1- I mitan Dl,,-** jlp-i - .,at-.,- t 0 ..n 1 "e" 8 C of Hottest Part a Max - 0 I t.... N at:: at Part of 700 0 Contours ( ) 4000 Contours Coal train Paper Bum ( T aP. ? p. Tj 700 C Coritours 400 C Contour. Coal from Paper Bum F- we.) c) (-) (-) 6 7 76o 760 4 6 8 790 800 5 8 6 8 815 830 5 6 6 11 8 1 790 800 5 T 19 LSPOO 1 TABER 3 TEMPERNMWE MHAMMD%MS 3 Vuffs Der minute. 35 ml Duff Puff Code No. Thermocouple Mean M-lsium Mwdmum Temp, Temp (06 C RL 268 1 VO 815 2 760 T75 3 T50 750 RL2268C 1 825 2 830 845 3-- 650 700 3 b- 450 475 Distance Distance Approximate distance Mean Btn Between of Hotte.t Part of Maximum Maximum 70&C Contours YJO&C Contours Coal from Paper Wrn Temp. T 'P' (0 C) (.C 8.5 14.5 11 T90 800 T-5 13.5 T45 765 3.5 12.5 2 65o 65o 10 A 11 810 825 9.5 15 9.5 Boo 820 - 6 2 520 540 5 3 0 Individual results - poor duplicates z 0 < (D 3 17 Distano Contour Moves Back on We 0; Cigarett e In 1.5 Sec. Dlwtanoe Between Code No 20&-70&C 200-C 40D*C 7000C RL 26B 1_3 1.5 1.8 5.5 PL 268c .1-3 0.7 0.7 4.8 Smoulder Distance Distance Approidmate distance Between Bt~.en of Hottest Part of 70&C Contours 4000C Contours Coal from Paper Burn 7 .13.5 11 5.5 13.5 8 - 10 5 8.5 14 8 15 9 6.5 3 Distance Between Code * Smoulder Rate Time for Distance -700*C 200 No RL 268 5.9 3.96 1.49 RL 268c 4.2 2.65 1.59 0 Unrealistic to use this swulder rate an steady smould- state not achieved at this puffing frequency 0 0 TABLE 4 I Dufr Per minute. 21S ml puff Puff Code No. Thermooo~ple "can Maxleaft Maximum To.p. D Temp. (oc) ( O TtL 26B 1 T90 2 775 80 3 845. 890. RL 26Bc 1 855 860 2 855 855 3 650 665 Distance Distance Approximate distance Mean Betsen Bt,4... of Ilottst Part of Maximum M..I- 700oC Contours 4 ooPC Contours Coal fr.. Paper Burn TemP. o Temp. (a C) c) ( 5 n 6 750 T50 6 9 7 T35 750 4 8 4 600 67!5 5 10 a 785 790 6 10 T T75 775 8 2 615 62o Unusually high - probably attributable to peripheral hot spots Smoulder DIstanoe Distance Approximate Distance Bt ... n Bt...n of Hottest Part of 700QC Contours 4000C Contours Coal from Paper Burn 3 10 6 3 9 7 - 9 4 10 4 10 T 7 4 ~9 ~lswl Va,r~~r~ htaa~, P-t P.- 0 log Ma,X;AO-K A -izulbelur- 6 W 1.0 CZ) NJ GN BATCo document for Province of British Columbia 5 November 1999 MeaA'% 7,a 6*0 Sao 1-4 PO-C BATCo document for Province of British Columbia 5 November 1999